In a physical medium, it's way cheaper and easier to make light color thing dark than make a dark colored thing light. "Dark mode" books would require dyeing each sheet black, then painting the text on top of each sheet, rather than what is currently done, where we bleach each sheet white, then dye the text into each sheet.
Somewhat related - this is why printers use CMYK, rather than RGB. Computer screens use pure light, so they simply emit whatever combination of light they need to, and your eyes add them together. In a physical medium, however, what we see is based on what is reflected, i.e. not absorbed. Hence, each color of ink, in additive terms, is two colors together (cyan is green+blue, magenta is red+blue, etc). When you combine CMYK colors, you can precisely control what wavelengths of light are being absorbed in order to reflect the correct color.
Same reason that it's uncommon for any page to have most of the page covered in ink, regardless of whether it's a book or a sheaf of papers or whatever. Ink costs something, and it's cheaper to put ink on a little bit of the page than it is to put ink on everything but a little bit of the page. Unless there's a compelling reason to do otherwise, you take the cheaper route.
Ohh, that explains the really rich, deep colors they always used in the backgrounds. I loved the moody atmosphere that show managed to capture. Way ahead of its time, especially for a kids' cartoon.
I'm a dark-mode person on computers, and I'm also a visual artist. When I draw digitally I always prefer drawing light colors onto a dark background, and when I paint I always prefer painting lighter colors onto a black-primed canvas. I think I first tried that after seeing a behind-the-scenes about Batman's artists doing it that way, and realizing it made much more sense to my visual and artistic sensibility.