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I'll likely just end up buying the same brand again, since they lasted me a good decade of frequent use, but what else is out there in the big and tall sizes that look great, have proper slacks closures and hems, use performance materials like microfiber/polyester, rayon, spandex, and have features like an expanding waistband. Synthetic fibers breathe well and keep you cook and dry and have superior stain resistance.
So what brands make nice slacks/dress pants out of performance materials with nice comfort features while still looking nice and stylish?
I'm not much help on the specific question, but I hate to have it die on the vine. So, I'll offer what advice I have.
I know a couple of people who shop at DXL and I've heard them recommend it to others, so I'd check with what they're offering. The guys that I know that shop there dress well.
The other place I'd look is Bonobos. They've got a wider selection of sizes than most retailers and I've been happy with everything I've bought from them.