According to Mindat, this is the Lomas Bayas disctrict, and the most prominent mine appears to be the Fortuna de Cobre, in a copper porphyry deposit. I would normally reach for malachite first, but it is not listed as found at any of the mines, so your main options are brochantite or (surprise!) atacamite.
Malachite can be eliminated for sure by testing with vinegar; it will effervesce slightly. Between brochantite and atacamite, there is considerable overlap in color, hardness, etc. You will have to get a lens and look for some crystals where the shape is distinct enough to determine if they are monoclinic (brochantite) or orthorhombic (atacamite).
You're absolutely right that it is copper porphyry ore (from an abandoned historical artisanal mine). However, I don't have the sample and cannot perform the tests beyond that point. Just wanted to kick-start the thread :)